2,2,2-Tribromo-N-phenylacetamide

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منابع مشابه

2,2,2-Tribromo-N-phenyl­acetamide

In the title compound, C(8)H(6)Br(3)NO, the N-H bond is anti to the carbonyl bond in the side chain. The N-H hydrogen atom is involved in a two-centered bond as it shows simultaneous N-H⋯Br intra- and N-H⋯O inter-molecular inter-actions in the structure. In the crystal, mol-ecules are packed into column-like chains along the b axis through the N-H⋯O hydrogen bonds.

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2,2,2-Tribromo-N-(4-methyl­phen­yl)acetamide

The asymmetric unit of the title compound, C(9)H(8)Br(3)NO, contains two independent mol-ecules which differ in the orientation of the tribromo group. A weak intra-molecular N-H⋯Br hydrogen bond is observed in each mol-ecule. In the crystal, the independent mol-ecules are linked into chains along the b axis by inter-molecular N-H⋯O hydrogen bonds.

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2,2,2-Tribromo-N-(2-chloro­phen­yl)acetamide

In the title compound, C(8)H(5)Br(3)ClNO, the conformation of the N-H bond is syn to the 2-chloro substituent in the benzene ring. There are no classical inter-molecular hydrogen bonds, but intra-molecular N-H⋯Br and N-H⋯Cl contacts occur.

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2,2,2-Tribromo-N-(3-methyl­phen­yl)acetamide

The asymmetric unit of the title compound, C(9)H(8)Br(3)NO, contains two independent mol-ecules. The conformation of the N-H bond is anti to the 3-methyl substituent in the benzene ring in each mol-ecule. The structure shows both intra-molecular N-H⋯Br and inter-molecular N-H⋯O hydrogen bonding, the latter leading to the formation of helical supra-molecular chains along the b axis.

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2,2,2-Tribromo-N-(3-chloro­phen­yl)acetamide

In the title compound, C(8)H(5)Br(3)ClNO, the conformation of the N-H bond is anti to the 3-chloro substituent in the benzene ring. An intra-molecular N-H⋯Br hydrogen bond occurs. In the crystal, mol-ecules are packed into infinite chains in the a-axis direction by N-H⋯O hydrogen bonds.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s160053680903298x